2Al + 6HCl -> 2AlCl₃ + 3H₂ (1)

ZnO + 2HCl -> ZnCl₂ + H₂O (2)

a) n_H2= 13,44/22.4=0.6(mol) -> mH2=0,6.2=1,2(g)

Theo PTHH: n_Al = 2/3 n_H2 = 2/3 . 0,6= 0,4(mol) -> m_Al = 0,4 . 27=10,8(g)

-> m_ZnO = 27-10,8= 16,2(g)

b) n_ZnO = 16,2/81=0,2(mol)

Theo PTHH (2): nHCl = 2nZnO=2.0,2=0,4(mol)

Theo PTHH (1) : nHCl=2nH₂=2.0,6=1,2(mol)

-> \(\Sigma\)nHCl = 0,4+1,2=1,6(mol)

-> mHCl = 1,6.36,5= 58,4(g)

-> mdd_HCl = 58,4.100/29,2= 200(g)

c) Theo PTHH (1): nAlCl₃ = 2/3 nH₂ = 2/3 . 0,6=0,4(mol)                                         -> mAlCl3=0,4.133,5=53,4(g)

mdd sau phản ứng= m_A + mddHCl - mH2 =27+200-1,2 =225,8(g)

-> C% AlCl3 = 53,4.100%/225,8 = 20,88%

Theo PTHH (2) nZnCl2 =nZnO= 0,2(mol)-> mZnCl2=0,2.136=27,2(g)

-> C% ZnCl2= 27,2.100%/255,8=10,63%

a, PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)

Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,4\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,4.27}{14,8}.100\%\approx72,97\%\\\%m_{MgO}\approx27,03\%\end{matrix}\right.\)

b, Ta có: \(n_{MgO}=\dfrac{14,8-0,4.27}{40}=0,1\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=n_{H_2}+n_{MgO}=0,7\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4}=0,7.98=68,6\left(g\right)\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{68,6}{10\%}=686\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,2\left(mol\right)\\n_{MgSO_4}=n_{MgO}=0,1\left(mol\right)\end{matrix}\right.\)

Ta có: m _{dd sau pư} = 14,8 + 686 - 0,6.2 = 699,6 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,2.342}{699,6}.100\%\approx9,78\%\\C\%_{MgSO_4}=\dfrac{0,1.120}{699,6}.100\%\approx1,72\%\end{matrix}\right.\)

nH2 = 6,72/22,4 = 0,3 (mol)

PTHH: 2Al + 6HCl -> 2AlCl3 + 3H2

nAl = 0,3 : 3 . 2 = 0,2 (mol)

nHCl (Al) = 0,3 . 2 = 0,6 (mol)

mAl = 0,2 . 27 = 5,4 (g)

%mAl = 5,4/25,65 = 20,05%

%mZnO = 100% - 20,05% = 79,95%

mZnO = 25,65 - 5,4 = 20,25 (g)

nZnO = 20,25/81 = 0,25 (mol)

PTHH: ZnO + 2HCl -> ZnCl2 + H2O

nHCl (ZnO) = 0,25 . 2 = 0,5 (mol)

nHCl (đã dùng) = 0,6 + 0,5 = 1,1 (mol)

CMddHCl = 1,1/0,1008 = 10,9M

C% = (10,9 . 36,5)/(10 . 1,19) = 33,43%

Tiếp bài của creeper nhé:

c. Ta có: \(n_{ZnO}=\dfrac{4,86}{81}=0,06\left(mol\right)\)

Theo PT₍₁₎: \(n_{HCl}=2.n_{ZnO}=2.0,06=0,12\left(mol\right)\)

Theo PT₍₂₎: \(n_{HCl}=2.n_{Zn}=2.0,1=0,2\left(mol\right)\)

=> \(n_{HCl}=0,12+0,2=0,32\left(mol\right)\)

=> \(m_{HCl}=0,32.36,5=11,68\left(g\right)\)

Ta có: \(C_{\%_{HCl}}=\dfrac{11,68}{m_{dd_{HCl}}}.100\%=12\%\)

=> \(m_{dd_{HCl}}=\dfrac{292}{3}\left(g\right)\)

Theo đề, ta có: 

\(D=\dfrac{\dfrac{292}{3}}{V_{dd_{HCl}}}=1,2\)(g/ml)

=> \(V_{dd_{HCl}}=81,1\left(ml\right)\)

C32: 

a, \(n_C=\dfrac{2,4}{12}=0,2\left(mol\right)\)

PT: \(C+O_2\underrightarrow{t^o}CO_2\)

Theo PT: \(n_{CO_2}=n_C=0,2\left(mol\right)\Rightarrow V_{CO_2}=0,2.22,4=4,48\left(l\right)\)

b, \(n_{NaOH}=0,3.1=0,3\left(mol\right)\)

\(\Rightarrow\dfrac{n_{NaOH}}{n_{CO_2}}=1,5\) → Pư tạo NaHCO₃ và Na₂CO₃

PT: \(CO_2+NaOH\rightarrow NaHCO_3\)

\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=n_{NaHCO_3}+n_{Na_2CO_3}=0,2\\n_{NaOH}=n_{NaHCO_3}+2n_{Na_2CO_3}=0,3\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}n_{NaHCO_3}=0,1\left(mol\right)\\n_{Na_2CO_3}=0,1\left(mol\right)\end{matrix}\right.\)

⇒ m_NaHCO3 = 0,1.84 = 8,4 (g)

m_Na2CO3 = 0,1.106 = 10,6 (g)

c, \(C_{M_{NaHCO_3}}=C_{M_{Na_2CO_3}}=\dfrac{0,1}{0,3}=\dfrac{1}{3}\left(M\right)\)

Lần sau bạn đăng tách câu hỏi ra nhé.

C31:

a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{14,6}.100\%\approx44,52\%\\\%m_{ZnO}\approx55,48\%\end{matrix}\right.\)

c, \(n_{ZnO}=\dfrac{14,6-0,1.65}{81}=0,1\left(mol\right)\)

Theo PT: \(n_{HCl}=2n_{Zn}+2n_{ZnO}=0,4\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{0,4.36,5}{10\%}=146\left(g\right)\)

a)\(n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

0,15    0,3                        0,15

\(m_{Zn}=0,15\cdot65=9,75\left(g\right)\)

\(\%m_{Zn}=\dfrac{9,75}{17,85}\cdot100\%=54,62\%\)

\(\%m_{ZnO}=100\%-54,62\%=45,38\%\)

b)\(m_{ZnO}=17,85-9,75=8,1\left(g\right)\Rightarrow n_{ZnO}=\dfrac{8,1}{81}=0,1mol\)

  \(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

  0,1         0,2

  \(\Rightarrow\Sigma n_{HCl}=0,3+0,2=0,5mol\)

  \(\Rightarrow V=\dfrac{0,5}{1}=0,5l=500ml\)

\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

\(2A1+2NAOH+2H_2O-2NaA10_2+H_2O\)

\(AI_2O_3=2NaOH+2NaOHA10_2+H_2O\)

\(n_{AI}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{3}.0,6=0,4\left(mol\right)\)

\(m_{AI}=27.0,4=10,8\left(gam\right);mAI_2O_3=31,2-10,8=20,4\left(gam\right)\)

Biết làm mỗi câu A

 Chỉ Có Al tác dụng với HCl sp tạo ra khí H₂

\(n_{H_2}=\dfrac{13.44}{22.4}=0.6\left(mol\right)\)
PTHH:
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
   0.4           \(\leftarrow\)                           0.6  (mol)

\(Al_2O_3+HCl\rightarrow AlCl_3+H_2O\)

n_Al=\(\dfrac{0.6\cdot2}{3}=0.4\left(mol\right)\)

m_Al=0.4*27=10.8(g)

=)) \(m_{Al_2O_3}=31.2-10.8=20.4\left(g\right)\)

\(\left\{{}\begin{matrix}\%Al=\dfrac{10.8}{31.2}\cdot100=34.62\%\\\%Al_2O_3=\dfrac{20.4}{31.2}\cdot100=65.38\%\end{matrix}\right.\)

a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)

Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{5,25}.100\%\approx51,43\%\\\%m_{Al_2O_3}\approx48,57\%\end{matrix}\right.\)

b, \(n_{Al_2O_3}=\dfrac{5,25-0,1.27}{102}=0,025\left(mol\right)\)

Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=0,45\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{0,45.36,5}{29,2\%}=56,25\left(g\right)\)

c, \(n_{H_2SO_4}=\dfrac{1}{2}n_{HCl}=0,225\left(mol\right)\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,225.98}{19,6\%}=112,5\left(g\right)\)